Polyimide pressure sensitive adhesive (PSA) tape is actually made up of two separate steps. The first is the manufacture of the polyimide film itself (the generic name of of DuPont’s tradename Kapton®), and the second is applying an adhesive backing depending on the intended application.
Polyimide Tape is made up of two separate steps. First is the manufacture of the polyimide film itself and the second is the application of the adhesive backing.
The Polyimide Film Manufacturing Process
Polyimide film, the generic name of of DuPont’s tradename Kapton®, is synthesized by polymerizing PMDA and ODA in strong polar solvents through the process of forming film and imine treatment at high temperature. This synthesis creates excellent physical, chemical, and electrical properties, as well as atomic radiation resistance, solvent resistance and low & high temperature resistance. It performs well in a wide range of temperatures as low as ‑452°F (-269°C) and as high as +500°F(+260°). Because of these characteristics, it is uniquely suitable for specific for many high temperature applications.
Manufacturing Polyimide Silicone PSA Tapes
Polyimide Silicone Adhesive Tape is made by first taking polyimide film and coating it with a heat-resistant silicone adhesive. Due to its stable pressure-sensitive macromolecule adhesive layer at high temperature, the tape offers excellent properties of heat resistance, electrical insulation, solvent resistance and radiation protection. Being silicone, it offers better elongation at break, and is used for electrical insulation of electrical equipment and high temperature insulation. It offers the highest heat resistance among film adhesive tapes, so it can also be applied for insulation in high-end electronic equipment, motors, and Lithium (Li) batteries. Other applications include the protection of the gold fingers on Printed Circuit Boards (PCBs) during wave soldering, as lead-free solders often require reflow temperatures up to 260°C — an operating temperature for which polyimide tape is uniquely suited — leaving no adhesive film once the tape is removed. Finally (though the true list of applications is nearly endless), it can be used for shielding in high temperature applications.
Manufacturing Polyimide Acrylic PSA Tapes
Polyimide Acrylic Tape is made using the same process as the silicone process described above, but though the acrylic is typically a heat-resistant acrylic, it still cannot withstand the high temperature range of the silicone PSA described above. Also, acrylics tend to be more brittle, so the lower temperature range is also somewhat more limited as the adhesive can crack at extremely low temperatures. However, since the polyimide acrylic tape still uses a base of polyimide, the film itself is still able to withstand a wide temperature range and can still be used in many of the same high-temperature applications; it is just that the adhesion properties of the film become more limited with an acrylic adhesive. Acrylic chemistries are typically cheaper materials also, so the final selling price of acrylic-based polyimide tapes are generally lower. Though CAPLINQ offers both acrylic-based and silicone-based tapes; given the marginal price difference and the wider range of applications, the most popular tapes remain the silicone-based polyimide tapes.
7 thoughts on “How is Polyimide Pressure Sensitive Tape Made?”
We have an application where we need to store a Li battery under seawater. We use a laminate pouch with an Al barrier layer and a Mylar (PET) coating on the outside. In time the seawater corrodes away the Al along the edges of the pouch ultimately causing the pouch to fail. We have found Kapton tape placed on the edges helps prevent the pouch from failing but I was wondering if you had information as to the best type Kapton to use to adhere to Mylar in a seawater environmen that would hold up the longest. What are your recomendations?
Silicone adhesive backed polyimide (Kapton) tapes have far superior resistance to water, including salt water and sea water. Silicones are naturally more resistant than acrylics to water (click here to read article comparing acrylics to silicones to rubbers).
Though acrylic adhesives have the highest adhesion to low-surface energy plastics, in my experience, the thin bondedge of acrylic adhesives slowly erodes when exposed for long periods of water.
They may start out stronger, but given time, silicone-based adhesives for Polyimide (kapton) tape are a better suited to this application. Contact us today for more information or to place an order.
In the article above, it states: “Polyimide film … creates excellent physical, chemical, and electrical properties, as well as atomic radiation resistance, solvent resistance and low & high temperature resistance. ” and “Polyimide Silicone Adhesive Tape … offers excellent properties of heat resistance, electrical insulation, solvent resistance and radiation protection. ”
Please quantify the radiation resistance and protection in terms of rad© using gamma (Co-60) irradiation.
You make a very good point. While it’s true that our polyimide tapes and films have excellent radiation resistance, these values should be quantified. This has been given to one of our engineers and the site will be updated when the information becomes available.
Please can i contribute or ask question in this forum