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Die Attach Film adhesives

Conductive and Insulating die attach films

AVAILABLE DIRECTLY AT CAPLINQ.COM

Die Attach Films

Henkel’s LOCTITE ABLESTIK conductive die attach film (CDAF) and non-conductive die attach films are leading the way in enabling customers to design products with controlled bondlines. Designers using Henkel’s die attach films are better able to control uniformity of bondline thickness and eliminate die attach fillets commonly found when using paste adhesives.

LOCTITE ABLESTIK conductive die attach films (CDAF) allow lead frame package manufacturers the same process advantages offered by non-conductive die attach film processes: controlled fillets, controlled bondlines, elimination of die tilt and better design latitude with the elimination of the die attach fillet.

Electrically Conductive Die attach film (CDAF) adhesives
Product	Description	Key attributes	Film thickness (um)	Moisture sensitivity level, MSL	Thermal conductivity (W/m-k)	In-package thermal resistance (K/W)
Loctite Ablestik CDF 200P Series	Ag-filled die attach adhesive	- Suitable for small die - Recommended for thin wafer handling applications - Oven cure	15 or 30	L1 260°C capable	2.3	1.5
Loctite Ablestik CDF 300P Series	Ag-filled die attach adhesive	- Suitable for small die - High adhesion - Good wetting - Oven cure	15 or 30	L1 260°C capable	1.0	2.1
Loctite Ablestik CDF 500P Series	Ag-filled die attach adhesive	- Good wetting and low warpage for large die - Recommended for thin wafer handling applications - Oven cure	15 or 30	L1 260°C capable	1.5	1.4
Loctite Ablestik CDF 600P Series	Ag-filled die attach adhesive	- Low stress and excellent wetting for large die - Compatible with various metal surfaces, including solder - Recommended for thin wafer handling applications - Oven cure	25	L2 260°C capable	1.0	2.1
Loctite Ablestik CDF 700P Series	Ag-filled die attach adhesive	- Suitable for small and medium die - High adhesion - Oven cure	15 or 30	L1 260°C capable	5.5	0.7
Loctite Ablestik CDF 800P Series	Ag-filled die attach adhesive	- Suitable for small die - Recommended for thin wafer handling applications - Oven cure	15	L1 260°C capable	3.4	0.7

Electrically Non-Conductive Dicing Die Attach Film (DDF) Adhesives
Product	Description	Key attributes	Dicing tape	Film thickness (um)	Wafer thickness (um)	Moisture sensitivity level, MSL	Modulus at 25°C (MPa)
Loctite Ablestik ATB 100 Series	Silica-filled, rubberized epoxy die attach adhesive	- Compatible with Cu wire or Au wire packages - Excellent wetting - Compatible with stealth dicing before grind (SDBG) process - Oven cure	Non-UV	15, 20, 25 or 30	Up to 75	L2 260°C capable	1,170
Loctite Ablestik ATB 100HA Series	Silica-filled, epoxy die attach adhesive	- Consistent dicing and die pickup for large die applications - No passivation damage - Compatible with stealth dicing before grind (SDBG) process - SkipCure	UV/Non-UV	5, 10, 15, 20, 25 or 30	Up to 50	L1 260°C capable	2,299
Loctite Ablestik ATB 100U Series	Silica-filled, rubberized epoxy die attach adhesive	- Compatible with Cu wire or Au wire packages - No passivation damage - Compatible with stealth dicing before grind (SDBG) process - Fast oven cure	Non-UV	5, 10, 15, 20, 25 or 30	Up to 75	L2 260°C capable	875
Loctite Ablestik ATB 100US Series	Silica-filled, epoxy die attach adhesive	- Consistent dicing and die pickup for large die applications - No passivation damage - Long thermal budget (4 hr. at 175°C) - Oven cure	UV/Non-UV	5, 10, 15, 20, 25 or 30	Up to 50	L2 260°C capable	1,277
Loctite Ablestik ATB F100E Series	Silica-filled, epoxy die attach adhesive	- Suitable for small to large die - Excellent workability for below 3mmX3mm die - Long work life (4 months before and after lamination) - Compatible with stealth dicing before grind (SDBG) process - Film over wire (FoW) and film over die (FoD) applications - Oven cure	UV/Non-UV	25 FoW: 35-80 FoD: 90- 150	Up to 75	L1 260°C capable	5,256

What is the composition of Die attach films

Conductive Die attach films

Polymer resins like epoxies, maleimides, bismaleimides, acrylates, silicone, cyanate esters have been used successfully in commercial films. And conductive fillers like gold, copper, silver, and nickel widely used.

Conductive die attach films are used as adhesives for circuit substrates, and heat sinks joined to metal or ceramic packages and PWBs. Silver-filled films are popular because of their high thermal conductivity in the order of 6 W/m·K. The typical electrical conductivities that make a film useful for EMI shielding lie in the range 5 × 10-3 to 5 × 10-4 ohm-cm.

Non conductive die attach films

Organic resins like epoxies, polyimides, bismaleimides, acrylates, silicone, cyanate esters and non-conductive fillers like silica, alumina, aluminum hydroxide, mica, glass, and organic fillers like PET have been used in manufacturing NCF.These films are electrically insulating to ensure the electrical integrity of circuits. They are used for maintaining the physical connection between the electrode pads and bumps in chip on board (COB) and chip on glass (COG) applications, and for safeguarding fine pitch devices.

Their thermal conductivity (1.5–1.6 W/m·K) comes into play for bonding heat-dissipating components to heat sinks.Manufacturers have also combined NCF and dicing tape into a single product to automate wafer processing and assembling

Conductive Die attach films

Conventional die attach pastes are still plagued by inconsistencies that lead to voids, bleeds and uneven bondlines in assembled packages. This unreliability is an issue because the demand for smaller-sized semiconductor packages with increased functionality, like those used in many handheld electronics, keeps growing. Small-sized packaging calls for reduced footprint on a printed circuit board. This is accomplished by assembling multiple dies in the same package. When die attach pastes are used for die stacks, especially with difficult die-to-pad ratios, the challenges mentioned above can result in low yields.

Die attach films were created to solve the inconsistency issue in multichip modules and other applications involving wafer-level and die size limitations (e.g., thin dies ~100µm). In general, any situation where the problem of too little, or too much die paste can give rise to resin spreading (contaminating the die), large fillet formation (problematic for close die configurations), and resin overflow (causing poor wire bonding), films are the preferred solution.

Composition of conductive die attach film, DAF

Looking at their core ingredients, conductive die attach films are fundamentally similar to paste versions. They are made from organic resin that may be thermoplastic or thermosetting, incorporated with a conductive filler, and dried into sheets/film of thickness ranging anywhere between 10-40 µm. Polymer resins like epoxies, maleimides, bismaleimides, acrylates, silicone, cyanate esters have been used successfully in commercial films. And conductive fillers like gold, copper, silver, and nickel widely used.

Preparation of DAF

In general, a pre-mixed composite similar to die attach paste is coated onto a release liner, and together they are laminated to a reinforcement/carrier such as PVC or glass fabric. This provides structural support during fabrication and handling. Alternatively, for wafer-level applications, the resin composite plus carrier are laminated with dicing tape to produce dicing die attach film. It streamlines manufacturing and makes automation feasible, where cut wafer pieces are easily picked and positioned.

Film makers ensure the DAF and dicing tape have good bonding, and at the same time, the tape can be released without leaving residue on the film. UV and thermal release films are popular for this reason. Conductive die attach film can be purchased as:

Sheets or rolled sheets (e.g., 500 sheets per roll) that the user will cut into the desired shape to fit the die.
Pre-cut sheets, sized for specific devices.
Pre-attached to leadframes and substrates for extra convenience.

Properties that can affect conductive die attach film selection

Die mounting temperature

Supplier recommendations for bonding temperatures are a good place to start. The stipulated temperatures show the strongest bonding strength for specified materials. However, because the surfaces to be bonded can vary (roughness, type of material and level of contamination), the die attach process will need to be tested for each new product before scaling production.

Therefore, optimization is necessary to determine the bonding force, temperature, and bonding time that will achieve the strongest bond possible with minimum bondline thickness and negligible voids.

Tg, viscosity, and low stress

The stress characteristics of packages with film adhesives are a function of CTE, elastic modulus, and Tg to varying degrees.

Low modulus DAF can absorb a large amount of stress before fracture occurs. However, because the modulus for thin films at high temperatures is difficult to determine, adhesion at high temperatures is an important parameter when selecting a DAF variant. A DAF with high Tg is recommended at high temperatures. The Tg is the point (range) where the film changes from glassy solid to rubbery. As such, operating close to Tg means that the reliability of an assembly can become compromised. Testing the elastic modulus of a DAF at different temperatures is important.

Dicing

Optimizing the dicing parameters ensures dicing occurs with minimal chipping, cracking, or flying die. Die fly when the adhesion between DAF and dicing tape isn't strong enough. On the other hand, too strong an adhesion will lead to difficulties for die pick up. Appropriate film selection makes a trade-off between these competing challenges.

Good wetting

For handling thin wafers and large die sizes, films characterized with excellent wetting are recommended to enable complete and robust adhesion to substrates. This removes the need to apply excessive pressure that may damage the wafer. On the other hand, poor adhesion in large die can lead to warping and other problems.

Compatibility

For wafers, a film that is compatible with the various wafer processing stages will add a higher level of flexibility and performance to the manufacturing process. For other applications, the type of resin a film is composed of should agree with the substrate, whether metal, glass, ceramics or organics and also the end-use device. The manufacturer's guidelines will prove useful here.

Curing

With every application of heat, the film gets partly cured. This is not a significant issue for processes with few heating steps. However, for multichip packages, the total heat applied for heat treatment at wafer lamination, die attach and wire bonding needs to take into account the curing required for molding. There's a risk of delamination when attempting to mold packaging with fully cured DAF.

Certain films need heat and pressure to be applied simultaneously during curing, e.g., anisotropic films (so that metal filler particles become aligned) or where plastic substrates are involved (so that trapped air and volatiles can be pushed out). Techniques for preventing trapped air or moisture bubbles include curing under vacuum and vacuum baking surfaces before adhesion.

Storage:

DAF contains UV-sensitive components. Therefore, exposure to ambient light for periods of time can initiate curing. Rolled film can be stored from 6 months to a year (depending on the manufacturer) in a dark place before it loses its effectiveness.

Ideally, based on their storage time and minimum order quantity, DAF is suited to large scale manufacturing where these requirements will be matched by production volume to prevent wastage.

Non-conductive die attach films

The first die attach films to be manufactured were non-conductive. Moreover, their prices are not as prohibitive as conductive variants. Non-conductive films are useful for many of the same reasons: for preventing adhesive bleeding, voiding, and inconsistencies with bond line thickness.

They are required wherever multiple bare chips are to be stacked on top of one another since smaller package sizes help improve signal integrity and thermal path in modern packaging technology. Examples are 2.5D and 3D-TSV system in package (SIP) applications for high-end memory storage.

Advantages of non-conductive die attach films

The importance of no fillet in thin, small die and multiple die packaging

In traditional die attach paste applications, the leadframe pad is larger than the die. The applied paste flows and forms a fillet around the die edge but must not spread past and flow to the top surface of the die.

Die attach films make the dispensing step obsolete. In most cases, thermal compression bonding melts the film between a die and its substrate. As a result of negligible fillet formation or bleeding, die attach films are suitable for configurations demanding tighter clearance between die and die pad, making it possible to incorporate more die per package, such as in LGA and PBGA. In comparison, using pastes, larger die pad sizes means fewer dies per package are possible.

Processing and manufacturing are easier to control

A wafer already backed by die attach film eliminates the need to apply paste to individual die, essentially removing a repetitive stage from the manufacturing process. Also, no second guessing the thickness of the applied adhesive is required. The film thickness decides the width of bondlines.

The drawbacks of film are their higher price, the need for additional equipment, and generally, their lower thermal and electrical conductivity compared to paste variants. However, manufacturers are still coming up with films having higher thermal conductivities than their previous film products.

Die sizes:

Initially developed for devices using die sizes less than 3x3mm, film manufacturers continue to push the boundaries so their products are suitable for a wider range of die sizes. You will find that often, suppliers offer different grades of dicing die attach film depending on the size of the die. For smaller die sizes (2x2mm), increased adhesion to the dicing tape is implemented to prevent die flying off during dicing. Die attach films for sizes less than 1x1mm and thickness less than 100 µm are now available commercially.

Composition of non-conductive die attach film, NCF

Non-conductive die attach films are made from either thermoplastic or thermosetting polymer resin that is incorporated with a non-conductive filler. The composite is coated on a liner, and laminated on a carrier (for support) using pressure and heat. Organic resins like epoxies, polyimides, bismaleimides, acrylates, silicone, cyanate esters and non-conductive fillers like silica, alumina, aluminum hydroxide, mica, glass, and organic fillers like PET have been used in manufacturing NCF.

These films are electrically insulating to ensure the electrical integrity of circuits. They are used for maintaining the physical connection between the electrode pads and bumps in chip on board (COB) and chip on glass (COG) applications, and for safeguarding fine pitch devices. Their thermal conductivity (1.5–1.6 W/m·K) comes into play for bonding heat-dissipating components to heat sinks. As such, diodes, transistors, resistors, and thermal-sensitive integrated circuits can be mounted reliably to PCBs. Manufacturers have also combined NCF and dicing tape into a single product for adding flexibility to automated wafer processing and assembling.

Properties that can affect non-conductive die attach film selection

Dielectric strength and dissipation factor

To provide the required electrical insulation, a NCF will be characterized by low dielectric constant and low dissipation factor. Dielectric strength measures the likelihood of the film breaking down when exposed to a high enough voltage and becoming conductive as a result. Suppliers will state the maximum voltage a component featuring their NCF film can experience and still continue to operate normally.

A low dissipation factor indicates low power losses and the corresponding low heating of circuit components in close proximity.

Curing

Cure temperatures provided in supplier data sheets should achieve complete polymerization of the NCF and the strongest adhesive strength. At temperatures other than what is provided, poor wetting and severe reliability issues can result. Temperatures between 125-150°C for 1-2 s are common, although there are specialized formulations with lower cure temperatures and faster cure times which are attractive for multichip modules.

Voiding, and CTE

Even though compared to paste variants, films exhibit low voiding, voids can become an issue when films are not applied properly (100% void-free is unlikely, 5% is acceptable in many applications). A few factors that can contribute to voiding are the NCF's viscosity, thermal stability, chemical stability, the evenness of the adhering surfaces, and moisture absorption especially for plastic substrates (plastics have uneven surfaces and are hydrophilic). To overcome voids, users will need to address these factors, e.g., through pressure application, substrate preparation, filler selection, and so forth

The mismatch of the CTE of different packaging materials is often the direct cause of warpage that leads to cracking. Used as an adhesive, the selected NCF should be lower than the CTE values of the die and substrate to minimize mechanical stresses after bonding. The presence of voids combined with thermal expansion can lead to film failure.

Good wetting

Storage

After UV exposure, some film variants deteriorate to such a level that the die pick up and place process is compromised. And due to their expense, it’s important to take into account the work-life of stored NCF.

Suitability to processing, and compatibility to various substrates

Wafers laminated with NCF will still need to undergo further processing conditions without degrading in adhesive and mechanical strength, or thermal properties, e.g., stealth dicing before grind (SDBG) process. Also, the selected film should exhibit excellent wetting and compatibility with typical substrates and applications, e.g., Cu and Au wire packages, solder masks, etc.